Lecture Organic chemistry - Chapter 14: Delocalized Pi systems. After studying this chapter you will: Be able to identify, without explicit prompting, when delocalization is important, or not, be able to discuss the special characteristics benzene, be able to predict the products from a Diels-Alder reaction and be able to recognize a set of reactants and conditions as those belonging to the Diels-Alder reaction.

 48 p husc 25/07/2016 209 1 Download

Lecture Organic chemistry - Chapter 15: Benzene and aromaticity. In this chapter, we will explore the structural implications of the stabilizing effects of aromaticity. The discussion will introduce the key ideas by focussing on the unique properties of benzene, the prototypical aromatic molecule. One new chemical reaction appears, electrophilic aromatic substitution, of benzene (using a variety of reagents, leading to different products)....

 32 p husc 25/07/2016 259 1 Download

Lecture Organic chemistry - Chapter 16: Electrophilic attack on derivatives of benzene. This chapter presents the following content: Donors and acceptors, induction and resonance, induction, resonance, disubstituted benzenes-higher substitution, the strongest activator wins,...and other contents.

 31 p husc 25/07/2016 249 1 Download

Chapter 17 provides knowledge of aldehydes and ketones. In this chapter, the following content will be discussed: Nomenclature, systematic naming (IUPAC), structure, synthesis, reactions, hydration: geminal diols,...and other contents.

 45 p husc 25/07/2016 197 1 Download

Chapter 18 provides knowledge of enols, enolates, enals, and enones. The main contents of this chapter include all of the following: Keto-enol equilibria, aldol condensation, intramolecular aldol, preparation,...and other contents.

 42 p husc 25/07/2016 160 1 Download

Lecture Organic chemistry - Chapter 19: Carboxylic acids. The following will be discussed in this chapter: Naming: alkanoic acids, resonance, acidity, oxidation of primary alcohols and aldehydes, carbonation: organometallic reagents and carbon dioxide, nitrile hydrolysis,...and other contents.

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Lecture Organic chemistry - Chapter 20: Carboxylic acid derivatives. The main contents of this chapter include all of the following: Inductive effects, resonance effects, acyl halides, reactions, anhydrides, esters, amides

 43 p husc 25/07/2016 228 1 Download

After attending lectures, reading the text and working assigned problems related to this chapter, students will have acquired the following knowledge and abilities: Given the IUPAC name for a compound containing an amine functional group, be able to draw its structure; know the orbital mechanism for inversion at a pyramidal amine nitrogen; know how the relative electronegativity of N vs. O affects the boiling point, solubility, and basicity of...

 27 p husc 25/07/2016 220 1 Download

Chapter 22 - What does the benzene ring do to its substituents? After attending lectures, reading the text and working assigned problems related to this chapter, students will have acquired the following knowledge and abilities: Given the IUPAC name of a phenol derivative, be able to draw its structure; know how resonance influences the stability of benzylic cations, anions, and radicals as compared to similar non-benzylic species; be able to...

 38 p husc 25/07/2016 193 1 Download

Chapter 24 - Carbohydrates. After completing this chapter, students will be able to: Given a molecule in a fisher projection, be able to convert it to a wedge/dash representation and vice versa; given a hexopyranose, be able to determine the configuration of the anomeric carbon stereocenter as α or β.

 29 p husc 25/07/2016 245 1 Download

After attending lectures, reading the text and working assigned problems related to this chapter, students will have acquired the following knowledge and abilities: Know the origin of the unusual acidity of H α atoms located between two carbonyl groups, know the relative acidity of H α in aldehydes, ketones, esters, and 1,3-dicarbonyls; given starting material and reaction conditions, predict the major product that will form;...

 26 p husc 25/07/2016 198 1 Download

Lecture Organic chemistry - Chapter 25: Heterocycles. In this chapter, the following content will be discussed: Intramolecular SN2 reaction, special reaction for oxacyclopropanes, heterocyclopentadienes: pyrrole, furan, and thiophene; synthesis of heterocyclopentadienes,...and other contents.

 22 p husc 25/07/2016 233 1 Download